Do you have an nvidia cuda equipped graphics card in your computer, as Octane will only work with one?
You might be better off trying the latest Octane demo release v1.0 as this works with the latest kepler video cards (if that's what you actually have) and maybe looking on the Octane forum for help too.
Have a good read of the user manual, or you'll not get very far!
**EDIT**
Go to Menu > File > Preferences... Cuda Devices tab, and be sure to enable your card.
Martin.
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