First create a solid of the larger ring, with its gap. 
Second, sweep the small circle to 100% of the gap, and close its ends, to make a solid. 
Boolean union the two solids.  Result is one ring with smaller diameter in previous gap.  Delete or hide the curves.  Use the edges to fillet. 
Fillet the 4 edges.  Total available radius to fillet is 7.5mm - 6.5mm = 1mm, 
so the sum of the inner and outer fillets should be at most, 1mm. 
 
- Brian 
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