Yes, have the free Version "Expression 3.3" but no
Link where you could download it. Seems no more
avaible.

Alternative could be the also free Microsoft Epression Design 4.
Works on Win 10, it even have more Brushes. Very cool ones.
Here Link:
https://www.heise.de/download/product/expression-design-41150/download

Its a german Site ( because i am german ;) ) , Use the download button below.
The upper one does not work. Is named as Trial but its the full working free Version.