Hi Matt, all of the UI is made up of bitmap files and settings in CSS files, which are under the \ui sub-folder inside of the main installation folder. 
So it is possible to change the appearance by making a new skin that has different bitmaps and CSS settings.
 
But it is a fair amount of work to do so, it's not like there is a checkbox somewhere that you just click to "make things dark".
 
For an example check out this previous thread:
 http://moi3d.com/forum/index.php?webtag=MOI&msg=1521.1
    - Michael  
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